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71.
T. M. Zubareva T. M. Prokop’eva I. V. Kapitanov I. A. Belousova N. G. Razumova A. F. Popov 《Theoretical and Experimental Chemistry》2007,43(4):247-254
Neutral forms of hydroxylamine, N-methylhydroxylamine, and N,N-dimethylhydroxylamine are typical α-nucleophiles in water.
In comparison with aryl anions of similar basicity their rate of reaction in the decomposition of 4-nitrophenyl diethylphosphonate
is increased by about 102 times. Decomposition of the substrate is accelerated in cetyltrimethylammonium bromide micelles (about 4 to 30 fold). Hydroxylamine
and its N-alkyl derivatives are the most effective low basicity nucleophiles. The sole factor responsible for the micellar
effects is the concentration of the reagent in the surfactant micelles.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 4, pp. 231–236, July–August, 2007. 相似文献
72.
L. D. Popov Yu. P. Tupolova S. I. Levchenkov V. V. Lukov V. A. Kogan 《Russian Journal of Coordination Chemistry》2007,33(3):208-212
A series of novel mono-and binuclear copper(II) complexes with substituted salicylaldehyde acylhydrazones H2L of the formula CuL · xH2O (x = 0 and 1) and [Cu(HL)](ClO4)(CH3OH) were synthesized. The isolated dimeric complexes of copper acetate were found to exist as isomers with different bridging atoms. In dimers showing a superexchange between the paramagnetic centers through bridging phenoxide O atoms, the antiferromagnetic exchange couplings were much stronger than those in complexes with bridging O atoms of the a-oxyazine fragment. 相似文献
73.
Krause M Popov VN Inakuma M Tagmatarchis N Shinohara H Georgi P Dunsch L Kuzmany H 《The Journal of chemical physics》2004,120(4):1873-1880
Metal-carbon cage vibrations of crystalline endohedral D2d-M2@C84 (M=Sc,Y,Dy) dimetallofullerenes were analyzed by temperature dependent Raman scattering and a dynamical force field model. Three groups of metal-carbon cage modes were found at energies of 35-200 cm(-1) and assigned to metal-cage stretching and deformation vibrations. They exhibit a textbook example for the splitting of molecular vibrations in a crystal field. Induced dipole-dipole and quadrupole-quadrupole interactions account quantitatively for the observed mode splitting. Based on the metal-cage vibrational structure it is demonstrated that D2d-Y2@C84 dimetallofullerene retains a monoclinic crystal structure up to 550 K and undergoes a transition from a disordered to an ordered orientational state at a temperature of approximately 150 K. 相似文献
74.
Sharutin V. V. Pakusina A. P. Egorova I. V. Platonova T. P. Bukvetskii B. V. Popov D. Yu. 《Russian Journal of Coordination Chemistry》2002,28(12):827-830
Tetraphenylantimony nitrite was synthesized by reacting pentaphenylantimony with triphenylantimony dinitrite at a molar ratio of 1 : 1 in toluene, and its structure was determined using X-ray diffraction analysis. The Sb atom is coordinated to the oxygen atom of the axial nitrite group to form a trigonal bipyramid. The Sb–C(Ph)eq distances vary within the 2.103–2.111(3) Å range, and the S–O(1) and Sb–C(41) bond lengths are equal to 2.386(3) and 2.156(3) Å, respectively. The Sb...N distance and the axial C(41)SbO(1) angle are equal to 3.133(4) Å and 174.7(1)°, respectively. 相似文献
75.
I. I. Popov A. M. Simonov S. N. Kolodyazhnaya 《Chemistry of Heterocyclic Compounds》1970,6(11):1463-1465
3-(1-Methyl-2-benzimidazolyl)acrylic acid was obtained by the reaction of 1,2-dimethylbenzimidazole with chloral and subsequent hydrolysis of the condensation product. The hydrochloride of the chloride of this acid and its esters and amides were synthesized. The methyl and ethyl esters of the acid were synthesized by the Wittig reaction. The IR and UV spectra of the compounds obtained are presented.See [9] for Communication XXIV.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1566–1568, November, 1970. 相似文献
76.
Simanenko Yu. S. Popov A. F. Karpichev E. A. Prokop'eva T. M. Savelova V. A. Bunton C. A. 《Russian Journal of Organic Chemistry》2002,38(9):1314-1325
1-Cetyl-3-(2-hydroxyiminopropyl)imidazolium chloride and bromide were synthesized for the first time. These compounds are functionalized zwitterionic surfactants which give rise to micelle formation in aqueous solution. Kinetic and thermodynamic analysis of nucleophilic cleavage of p-nitrophenyl p-toluenesulfonate, diethyl p-nitrophenyl phosphate, and ethyl p-nitrophenyl ethylphosphonate in the presence of 1-cetyl-3-(2-hydroxyiminopropyl)imidazolium halide micelles showed that the latter are powerful nucleophilic reagents whose kinetic behavior can be described in terms of a simple pseudophase distribution model. The efficiency of substrate solubilization with zwitterionic surfactant micelles and the reactivity of the oximate fragment in the micelle phase were estimated on a quantitative level. The observed acceleration of SN2 reactions with the examined p-nitrophenyl esters relative to analogous reactions of zwitterionic 1-methyl-3-(2-hydroxyiminopropyl)imidazolium halides is, respectively, 12800, 550, and 900 times; it is explained mainly by increased concentration of the reactants in micelles. 相似文献
77.
Fireman-Shoresh S Popov I Avnir D Marx S 《Journal of the American Chemical Society》2005,127(8):2650-2655
Enantioselective surfactant-templated thin films were fabricated through the sol-gel (SG) process. The enantioselectivity is general in the sense that it discriminates between pairs of enantiomers not used for the imprinting process. The chiral cationic surfactant (-)-N-dodecyl-N-methylephedrinium bromide (1) was used as the surfactant template, and after its extraction chiral domains were created. The chiral discriminative feature of these films was examined by challenging with pure enantiomer solutions for rebinding. Selective adsorption was shown using (R)- and (S)-propranolol, (R)-2 and (S)-2, respectively, and (R)- and (S)-2,2,2-trifluoro-1-(9-anthryl)ethanol, (R)-3 and (S)-3, respectively, as the chiral probes. The selective adsorption was measured by fluorescence analysis, and the chiral selectivity factors were found to be 1.6 for 2 and 2.25 for 3. In both cases, (R)-enantiomer was adsorbed preferably. The resulting material was characterized by transmission electron microscopy, by diffraction, and by surface area measurements, and was found to be semicrystalline with short-range ordered domains (50 A) of hexagonal symmetry. 相似文献
78.
K.S. Morley N.V. Tokareva V.K. Popov J. Zhang S.M. Howdle 《European Polymer Journal》2007,43(2):307-314
A supercritical fluid (SCF) route for facile and homogeneous introduction of silver nanoparticles into polymer hosts is described. Our focus is on ultra-high molecular weight polyethylene (UHMWPE). We demonstrate that the metallic nanoparticles have a substantial effect upon the wear and tribochemical properties of the polymer substrate. 相似文献
79.
Smetanina O. F. Kuznetzova T. A. Denisenko V. A. Pivkin M. V. Khudyakova Yu. V. Gerasimenko A. V. Popov D. Yu. Il"in S. G. Elyakov G. B. 《Russian Chemical Bulletin》2001,50(12):2463-2465
A pentacyclic tritepenoid, 3-methoxyolean-18-ene (miliacin), was isolated for the first time from the marine fungus Chaetomium olivaceum. Its structure was determined on the basis of 2D NMR spectroscopy and X-ray diffraction data. 相似文献
80.
The Ward correspondence between self-dual Yang-Mills fields and holomorphic vector bundles is used to develop a method for reducing the Lax pair for the self-duality equations of the Yang-Mills model ind=4 with respect to the action of continuous symmetry groups. It is well known that reductions of the self-duality equations lead to systems of nonlinear differential equations in dimension 1d3. For the integration of the reduced equations, it is necessary to find a Lax pair whose compatibility conditions is these equations. The method makes it possible to obtain systematically a Lax representation for the reduced self-duality equations. This is illustrated by a large number of examples.N. N. Bogolyubov Theoretical Physics Laboratory, JINR, 141980 Dubna, Russia. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 102, No. 3, pp. 384–419, March, 1995. 相似文献